Continuous decentralized hydrogen production through alkaline water electrolysis powered by an oxygen-enriched air integrated biomass gasification combined cycle

Abstract

This research work presents an innovative approach for continuous decentralized production of renewable hydrogen from woody biomass. Alkaline water electrolysis (AWE) is used to produce high-purity hydrogen, while the oxygen by-product is mixed with ambient air and used to fire a biomass-fueled downdraft gasifier in order to produce an upgraded producer gas with a lower heating value (LHV) between 7–8 MJ/Nm³. This fuel gas is then subjected to a conditioning stage and eventually fed to a combined cycle consisting of a recuperative gas turbine as topping unit and a regenerative subcritical organic Rankine cycle as bottoming unit, which together allow for a combined electric power generation efficiency close to 40%. Most of the net AC power from the integrated gasification combined cycle (IGCC) is rectified to DC power and ultimately used to power an alkaline electrolyzer, with a minor share allocated to all the required utilities and ancillary equipment, including hydrogen compression to 200 bar. The results from simulation of the hybrid IGCC-AWE plant under steady-state operating conditions in Aspen Plus V.11 indicate an optimal efficiency of 17.6% based on the LHV of hydrogen. Thus, if sized for a biomass consumption of 1 t/h, the proposed plant is capable of providing around 26 kg/h of compressed hydrogen at 200 bar.