Examinando por Autor "Hermoso-Orzaez, Manuel Jesus"
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Ítem Energy Recovery from Polymeric 3D Printing Waste and Olive Pomace Mixtures via Thermal Gasification—Effect of Temperature(MDPI, 2023-02) Diaz-Perete, Daniel; Hermoso-Orzaez, Manuel Jesus; Carmo-Calado, Luis; Martin-Doñate, Cristina; Terrados-Cepeda, JulioOne of the polymeric materials used in the most common 3D printers is poly(ethylene terephthalate) glycol (PETG). It represents, in world terms, around 2.3% of polymeric raw material used in additive manufacturing. However, after processing this material, its properties change irreversibly. A significant amount of waste is produced around the world, and its disposal is usually destined for landfill or incineration, which can generate an important issue due to the high environmental risks. Polymer waste from 3D printing, hereinafter 3DPPW, has a relatively high calorific value and adequate characteristics to be valued in thermochemical processes. Gasification emerges as an innovative and alternative solution for recovering energy from 3DPPW, mixed with residues of lignocellulosic origin, and presents some environmental advantages compared to other types of thermochemical treatments, since the gasification process releases smaller amounts of NOx into the atmosphere, SOx, and CO2. In the case of the study, co-gasification of olive pomace (OLB) was carried out with small additions of 3DPPW (10% and 20%) at different temperatures. Comparing the different gasifications (100% OLB, 90% OLB + 10% 3DPPW, 80% OLB + 20% 3DPPW), the best results for the synthesis gas were obtained for the mixture of 10% 3DPPW and 90% olive pomace (OLB), having a lower calorific value of 6.16 MJ/m(3), synthesis gas yield of 3.19%, and cold gas efficiency of 87.85% for a gasification temperature of 750 degrees C. In addition, the results demonstrate that the addition of 3DPPW improved the quality of syngas, especially between temperatures of 750 and 850 degrees C. Including polymeric 3D printing materials in the context of the circular economy and extending their life cycle helps to improve the efficiency of subsequent industrial processes, reducing process costs in general, thanks to the new industrial value acquired by the generated by-products.Ítem WEEE polymers valorization, its use as fuel in the gasification process and revaluation of the inert by-products obtained: Sustainable mortars as a solution(Cell Press, 2023-09) Diaz-Perete , Daniel; Hermoso-Orzaez, Manuel Jesus; Terrados-Cepeda, Julio; Silva-Romano, Pedro; Martin-Doñate, CristinaThe global production of polymer materials has exploded in the last few decades. Their mechanical properties, erosion and corrosion resistance, good performance as insulation materials, and their ease and flexibility of manufacturing have made polymers one of the most widely used materials in the industry and in daily life. Several institutions and governments are beginning to raise serious environmental and ecological concerns with international impact soon, due to the increasing level of polymer production, which does not seem to be slowing down. It is necessary for the scientific community to make efforts in the development and evaluation of new methodologies to enable the inclusion of these types of materials in the circular economy of various production sectors. This is important in order to reduce the ecological impact caused by the current global production level of polymers. One of the most used methods for the recovery of polymeric materials is energy valorization through thermochemical processes. An example of this is thermal gasification using fuels composed of biomass and a mixture of polymeric waste from electrical and electronic equipment (WEEE). Through this thermochemical process, high-energy value synthesis gas, with a high concentration of hydrogen, is obtained on one hand, while waste products in the form of chars, ashes and slag are generated on the other hand. This manuscript presents a detailed study methodology that begins with chemical analysis of the raw material and includes subsequent analysis of mechanical results for the revaluation of these residual inert by-products, using them as partial substitutes in cement clinker to produce building mortars. This described methodology influences directly in the LCC (Life Cycle Costing) of final designed products in plastic and extend material life cycle Plastic materials are here to stay, so the study and optimization of polymer waste recovery processes are vital in achieving the Sustainable Development Goals (SDGs) set by the European Union in terms of efficiency and sustainability. It is also the only possible way to create an environmentally sustainable future world for future generations. After applying the described methodology, the mechanical test results show that the modified mortars exhibit established behaviour during the hardening time and similar strength growth compared to commercial mortars. The maximum mechanical strengths achieved,including compressive and flexural strength, make modified mortars a viable choice for several applications in the civil engineering sector.