DEIO-Artículos
URI permanente para esta colecciónhttps://hdl.handle.net/10953/197
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Examinando DEIO-Artículos por Autor "Cotes, Teresa"
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Ítem Study of the synergistic impact of Fe3O4, Na2CO3 and organic C on kaolin-based lightweight aggregates by a DOE (Mixture Experiments) approach(Elsevier, 2023-11-03) Moreno-Maroto, José Manuel; Cobo-Ceacero, Carlos Javier; Martínez-Rodríguez, Ana María; Conde-Sánchez, Antonio; González-Corrochano, Beatriz; Alonso-Azcárate, Jacinto; Uceda, Manuel; López-García, Ana Belén; Martínez-García, Carmen; Cotes, TeresaThe compositional synergies involved in the thermal formation of lightweight aggregates (LWAs) have been investigated through four pure phases: non-expansive kaolin (K); cork powder (C); sodium carbonate (N) and magnetite-Fe3O4 (M). Mixture Experiments has been applied for formulation, modeling and optimization. LWAs have been manufactured from 36 starting mixtures and the main technological properties have been characterized: bloating index (BI), particle density (ρrd), water absorption (WA24) and crushing strength (S). Maximum BI and WA24 together with minimum density are associated with the addition of a significant amount of iron phase in combination with small proportions of organic carbon (Optimal [BI > 60%]: 56.0% K + 40.2% M + 3.9% C + 0% N), while S increases antagonistically with expansion. Iron reduction by incomplete combustion of C appears to be critical in pore formation and concomitant bloating. N has enhanced the sphericity of the expanded specimens. The contrast between experimental and estimated data has shown that the models have generally performed very well.